Suzuki交叉偶联反应,Suzuki cross-coupling reaction
1)Suzuki cross-coupling reactionSuzuki交叉偶联反应
1.This dissertation mainly described two ligand-free cross-coupling protocols,including ligand-free palladium-catalyzedSuzuki cross-coupling reaction and copper-catalyzed Sonogashira cross-coupling reaction.本论文主要围绕在无配体条件下钯催化的Suzuki交叉偶联反应及铜催化的Sonogashira交叉偶联反应进行了较深入地研究。
2.TheSuzuki cross-coupling reaction is one of the most important methods for the construction of carbon-carbon bonds.Suzuki交叉偶联反应是构建碳-碳键的重要方法之一。
英文短句/例句
1.Amine-Promoted Transition Metals Palladium-Catalyzed Suzuki-Coupling Reactions;胺促进过渡金属钯催化的Suzuki交叉偶联反应研究
2.Preparing 2-(naphthalen-2′-yl) thiazole by Pd-Catalyzed Suzuki cross-coupling reactions钯催化Suzuki交叉偶联反应合成2-(2′-萘基)噻唑
3.Study of the Nickel Complex-Catalyzed Suzuki Cross-Coupling Reaction of Aryl Chlorides and Related Reactions;镍配合物催化氯代芳烃的Suzuki交叉偶联反应及相关反应研究
4.Palladium-Catalyzed Suzuki-Miyaura Cross-Coupling Reaction and Intramolecular Heck Reaction钯催化Suzuki-Miyaura交叉偶联反应和分子内Heck反应的研究
5.The Study to Synthesize α,β-Unsaturated Esters Containing a Trifluoromethyl Group by Suzuki Cross-coupling;Suzuki型交叉偶联反应在合成含三氟甲基的α、β-不饱和酸酯中的应用研究
6.Studies on the Heck and Suzuki Coupling Reactions of Aryl Halides;卤代芳烃的Heck和Suzuki偶联反应研究
7.Research on Combinatorial Bimetallic Catalysis of Suzuki Coupling;组合双金属催化Suzuki偶联反应的研究
8.Recent Development of Suzuki Cross-Coupling Reaction in H_2O-TBAB System;水-TBAB体系中Suzuki偶联反应研究进展
9.Recent Developments of Suzuki Cross-Coupling Reaction in Aqueous Media;水相中Suzuki偶联反应研究进展
10.Study on Copper Catalyzed C-X (N, O, S) Cross-Coupling Reactions铜催化C-X（N，O，S）交叉偶联反应研究
11.Efficient C-S Cross Coupling Catalyzed by Cu_2OCu_2O催化的C-S交叉偶联反应的研究
12.Studies on the Suzuki Coupling Reactions and Condensation Reactions in Green Media.;绿色介质中Suzuki偶联反应和缩合反应的研究
13.The Synthesis of 3-Aryl-β-lactams via Suzuki Cross Coupling Reaction应用Suzuki偶联反应合成3-芳基-β-内酰胺类化合物
14.Research on the New Catalytic Systems for Suzuki and Heck Coupling Reactions of Aryl Halides;卤代芳烃的Suzuki与Heck偶联反应的新催化体系探索
15.Phosphoramidite-Transition Metal Catalyzed Cross-Coupling Reactions;亚磷酰胺—过渡金属催化的交叉偶联反应的研究
16.Amines as Ligands Promoted Palladium Catalyzed Cross-Coupling Reactions;胺为配体促进钯催化交叉偶联反应的研究
17.The Research of Kumada Cross-Coupling Reaction Catalyzed by Ultrafine Amorphous NiB Alloy;超细NiB非晶合金催化Kumada交叉偶联反应的研究
18.Study on Palladium-catalyzed Suzuki Cross-coupling Reaction in Aqueous Phase and Its Application in Synthesis of Bifenthrin水相中钯催化Suzuki偶联反应及其在联苯菊酯合成中的应用
相关短句/例句
Suzuki-Miyaura cross-coupling reactionSuzuki-Miyaura交叉偶联反应
1.The complex catalyzedSuzuki-Miyaura cross-coupling reaction of arylbromides with arylboronic acids in DMF-H2O using K2CO3 as a base to obtain substituted-biphenyl in yields of 75%~99%.以DMF-H2O为溶剂,K2CO3为碱,该络合物催化溴代芳烃和芳基硼酸的Suzuki-Miyaura交叉偶联反应合成取代联苯,收率75%～99%。
3)Suzuki cross-coupling reactionSuzuki交叉偶联
4)Suzuki coupling reactionSuzuki偶联反应
1.Preparation and application of SBA-15-supported palladium catalyst forSuzuki coupling reactions in supercritical carbon dioxide;SBA-15负载钯催化剂的制备及其在超临界二氧化碳介质中催化Suzuki偶联反应的研究
2.Nine compounds of lateral single fluorine substituted 4,4"-bis(trans-4-n-alkylcyclohexyl)biphenyl liquid crystals were synthesized viaSuzuki coupling reactions with 2-fluoro-4-(trans-4-alkylcyclohexyl)phenyl boric acid and(trans-4-n-alkylcyclohexyl)-bromo benzene as reactants.以2-氟-4-(反式-4-烷基环己基)苯基硼酸和烷基环己基溴苯为原料,采用Suzuki偶联反应合成了系列侧向单氟取代双烷基环己基联苯类液晶化合物9个,产品纯度均大于99。
5)Suzuki aryl-coupling reactionSuzuki偶联反应
1.NiCl2·6H2O was applied in theSuzuki aryl-coupling reaction for preparing 3-fluorin-4 ethylbiphenyl.在Suzuki偶联反应中用NiCl2。
6)Suzuki cross-coupling reactionSuzuki偶联反应
1.And then, describes thesis studies on theSuzuki cross-coupling reaction.本论文对Suzuki偶联反应的影响因素和研究进展进行了较详细的文献总结，并在此基础上对该反应进行了以下两个方面的系统研究：Ⅰ研究了二茂铁亚胺环钯化合物在Suzuki偶联反应中的应用本实验室在以前的研究中发现二茂铁亚胺环钯化合物是一类高效的环钯催化剂，对Heck反应、芳基汞的二聚、有机相中的Suzuki偶联反应都有较好的催化活性。
延伸阅读
交叉偶联反应分子式：CAS号：性质：一个有机分子与另一有机分子发生的不对称偶联反应。例如：烯丙基锂与2-氯辛烷可以发生交叉偶联反应生成4-甲基-1-癸烯。格利雅试剂、有机铝、有机锌、有机锡、有机铜、有机铅、有机汞等多种有机金属化合物也都可以与卤化烷等烃基化试剂发生交叉偶联反应，生成相应的不对称烃，是合成不对称烃，特别是单烷基芳烃和含有三级碳原子的链烃的有效方法。交叉偶联反应的范围很广，像芳烃重氮盐与苯酚或N,N-二甲基苯胺的偶联反应，也属于交叉偶联反应。
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